You may want to redact your personal data from those photos, such as your name, address, VRM and PCN number. I just tried to log into the appeals website with your details and it say the following:

The NtK is mostly PoFA compliant as far as I can see except for the "period of parking" being only specified as "the period immediately preceding...".
The NtD and the NtK both fail to comply with PoFA paragraphs 7(2)(a) and 8(2)(a) respectively, which require the notice to "specify the vehicle, the relevant land on which it was parked, and
the period of parking to which the notice relates."
The NtD and NtK provided by NTC do not specify a period of parking, but instead only give a single timestamp of 0948. A single point in time does not constitute a "period" of parking as required by law. The notices should indicate the duration during which the vehicle was allegedly parked.
If the alleged contravention states "Unauthorised parking" and the NtD or NtK only provide a single point in time without specifying the period of parking, it does not comply with the requirements of PoFA, even with the "unauthorised parking" allegation.
PoFA still mandates that the notice
must "specify the period of parking" regardless of the nature of the contravention, whether it's for overstaying, failing to pay, or "unauthorised parking." The reason is that the term "parking" inherently refers to a period during which the vehicle is stationary. Therefore, to prove "unauthorised parking", NTC must establish that the vehicle was parked for a
specific period without authorisation, not just at a single moment.
A single timestamp, such as 0948, does not show the vehicle was "parked" or unauthorised for a period of time, making it difficult to substantiate the contravention. The failure to specify a period of parking is non-compliant with the statutory requirements of PoFA.
However, you are dealing with an IPC member and no appeal (not that, apparently, they are giving you any chance to appeal anyway) is going to succeed with them or the IAS. You are going to have to sit this out, ignoring all reminders and debt collector letters and wait and see if/when they decide to issue a claim for the alleged debt. If/when they do, then come back and we can advise on how to defend any claim.
TO assist you in future, if/when they decide to try and make a claim, you are advised to get your own evidential photos of the entrance to the location and an overview of the actual car park area and a close up of the terms signs so that we can scrutinise them for breaches of contract law and the IPC Code of Practice (CoP).