You need to search the forum because I’m not going to do it for you, but if you appeal, the appeal will be rejected, then you’ll get letters from debt collectors with increasing amounts and scary words like “CCJ”. Eventually they’ll give up.
The notice probably doesn’t comply with the requirements of PoFA 2012, it seems only to have some bits, you you may get POPLA to cancel the charge on a second appeal on this basis, as long as you don’t name the driver. However your email to them has implicitly identified the driver.
PoFA is irrelevant at Stansted Airport, apologies, it’s not relevant land because it’s covered by byelaws.
PoFA only comes into its own if the driver is not known, by transferring liability to the registered keeper. It looks as if they know who both of them are now.