The NtK is not strictly PoFA compliant as there is no "invitation", nor any synonym of the word, for the keeper to pay the charge.
Paragraph 9(2)(e)(i) of Schedule 4 of the Protection of Freedoms Act 2012 states that the notice must explicitly invite the keeper to pay the unpaid parking charges. The wording must clearly convey this invitation, and mere implication or indirect suggestions are insufficient.
Others more wise than myself will undoubtedly be along to point out any other fatal flaws contained in the invoice you've received.